The Nature of
Gases
Goals for this
section:
-
Describe the assumptions of the kinetic theory as it
applies to gases
-
Interpret gas pressure in terms of kinetic theory
-
Define the relationship between Kelvin temperature and
average kinetic energy
-
Terms to know: kinetic energy, kinetic theory, gas
pressure, vacuum, atmospheric pressure, barometer, pascal (Pa), standard
atmosphere (atm)
I.
Kinetic Theory
a. The
word kinetic refers to motion
b. The
energy an object has because of its motion is called kinetic energy
c. According
to the kinetic theory, all matter consists of tiny particles that are in
constant motion.
d. 3
Assumptions of kinetic theory:
i.
The particles in a gas are
considered to be small, hard spheres with an insignificant volume
- This means only the volume between particles matters
- particle size doesn’t matter
- This means only the volume between particles matters
- particle size doesn’t matter
ii.
The motion of the particles in a gas is rapid,
constant and random
iii.
All collisions between particles in a gas are perfectly
elastic- this means there are no attraction
-
Particles are too far apart to be attracted to each other
II.
Gas pressure results from the force exerted by a
gas per unit surface area of an object
a. This
means: gas pressure is the result of simultaneous collisions of billions of
rapidly moving particles in a gas with an object.
b. An
empty space with no particles and no pressure is called vacuum .
c. Atmospheric
pressure results from the collisions
of atoms and molecules in air with objects in air with objects.
d. A
barometer is
a device that is used to measure atmospheric pressure.
III.
The SI unit of pressure is the pascal (Pa). However, kPa is usually used.
1000 Pa = 1 kPa
1000 Pa = 1 kPa
a. Standard
pressure is 101.3 kPa or 1 atm . This is also the pressure at sea level.
b.
IV.
Average Kinetic Energy
a. The
particles in any collection of atoms or molecules at a given temperature have a
wide range of kinetic energies. Most of the particles have kinetic energies somewhere
in the middle of this range.
b.
c. Absolute
zero (0 K, or –273.15°C) is the temperature at which the motion of
particles theoretically ceases.
i.
Particles would have no kinetic energy at absolute
zero.
ii.
Absolute zero has never been produced in the
laboratory.
d.
The
Kelvin temperature of a substance is directly
proportional to the average kinetic energy of
the particles of the substance.
i.
This
means that :
As temperature increases, KE increases As temperature decreases, KE decreases
As temperature increases, KE increases As temperature decreases, KE decreases
Notes on your own
- Properties of Gases (there are 8 questions)
Goals for this
section:
-
Explain why gases are easier to compress than solids
and liquids
-
Describe the 3 factors that affect air pressure
-
Explain how changes in these 3 factors result in
changes in air pressure
-
Terms to know: Compressibility
- Compressibility is a measurement of how much the volume
of matter decreases under pressure. When a person collides with an
inflated airbag, the compression of the gas absorbs the energy of the
impact.
- Why does a gas compress more than a solid or liquid? Because the space between particles in the gas is much greater than the distance between particles in liquid and solid. Also, under pressure, the particle in gas are forced closer together
- At room temperature, the distance between particles in an enclosed gas is about 10 times the diameter of a particle
- There are three things that can impact gas pressure. What are they? (hint: think about the warnings on aerosol cans, how your tires behave in the summer vs. the winter, how you change the pressure in your tires, and what happens to a balloon if you squeeze it)The amount of gas, volume and temperature. With raising the pressure exerted by a contained gas, it is reducing its volume. An increase in the temperature of an enclosed gas causes an increase in its pressure. If you inflate an air raft, for example, the pressure inside the raft will increase
- Four variables are generally used to describe a gas. The units and the symbol used to indicate the 4 variables are listed below. List what the symbol stands for.
- Pressure (P) in kilopascals
- volume (V) in liters
- Temperature (T) in kelvins
- the number of moles (n).
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